ETFE windows

post by bhauth · 2023-07-28T00:46:55.556Z · LW · GW · 4 comments

This is a link post for https://www.bhauth.com/blog/construction/ETFE.html

Contents

4 comments

Modern buildings have a lot of windows. If you look at a recent skyscraper, its facade is likely to be mostly glass. Why use glass for that? Why not use a sheet of plastic instead? Glass sheets are heavy and brittle; plastic film would be much lighter and cheaper.

The main problem with plastic film is UV degradation. Most plastic degrades over time when exposed to sunlight and air. Is it possible to make clear plastic with good resistance to UV and water? Could that be used instead of glass for buildings? Yes, and people have done that.

When ethylene and tetrafluoroethylene are polymerized together, they naturally tend to alternate, producing ETFE. Each carbon is either fluorinated or next to a fluorinated carbon, which increases UV resistance.

That wikipedia page lists some buildings using it, notably including the Eden Project and the "water cube". It also notes:

ETFE's first large-scale use architecturally came in 2001 at the Eden Project where ETFE was selected as it can be printed and layered to control solar conditions and because it was found to have a low friction coefficient, which saves on maintenance as dust and dirt do not stick.

Current ETFE building facades typically have 3 layers clamped at the edges with aluminum frame, with some air pumped between the layers. So, current designs typically use some electricity. The frames are more expensive than the ETFE film, and my understanding is that they result in ETFE being slightly more expensive than glass. Cost reduction of such frames seems possible.

ETFE has some notable advantages over glass:

There are also some ways in which ETFE is different from glass but not exactly better or worse:

Overall, I expect ETFE usage for buildings to increase significantly.

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comment by AnthonyC · 2023-07-28T01:39:26.612Z · LW(p) · GW(p)

So yes, from a materials performance POV. However, the world is starting to get serious about reducing PFAS pollution. For that reason alone I expect whole swaths of the world will limit use of ETFE and similar polymers outdoors at large scale.

For buildings where we do stick with glass, I hope to start seeing more smart glass, semitransparent photovoltaic glass, and hydrophobic coatings and textures. Those can to a lot to control heating, provide power, and reduce cleaning needs.

Replies from: bhauth
comment by bhauth · 2023-07-28T01:48:05.318Z · LW(p) · GW(p)

The PFAS problem isn't with polymers per se, it's with smaller compounds, primarily fluorosurfactants such as PFOS, which are used in things like stain-resistant carpet, stain-resistant pants, some grease-resistant biodegradable food containers, ski wax, some firefighting foam, etc.

Teflon can produce toxic compounds when heated, but it's normally inert, but the production process uses emulsion polymerization with fluorosurfactant, so it contains some. ETFE production probably uses fluorosurfactant too, but it seems much easier to find an alternative for ETFE production than for teflon. I think some branched alkane-ether or alkane-sulfonate surfactant would probably work well enough.

comment by bhauth · 2023-07-28T00:47:16.671Z · LW(p) · GW(p)

(what is this site for, anyway? [LW · GW])

Replies from: MondSemmel
comment by MondSemmel · 2023-10-04T15:10:26.791Z · LW(p) · GW(p)

Yup, I definitely appreciate this kind of post.